Study of thioglycosylation in ionic liquids
نویسندگان
چکیده
A novel, green chemistry, glycosylation strategy was developed based upon the use of ionic liquids. Research studies demonstrated that thiomethyl glycosides could readily be activated with methyl trifluoromethane sulfonate, using 1-butyl-3-methylimidazolium tetrafluoroborate as a solvent. This green chemistry glycosylation strategy provided disaccharides with typical yields averaging 75%. The ionic liquid solvent could be readily reused for five sequential glycosylation reactions with no impact on product yield.
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ورودعنوان ژورنال:
- Beilstein Journal of Organic Chemistry
دوره 2 شماره
صفحات -
تاریخ انتشار 2006